Fiddling with things that you don't understand, and having misaligned intuitions from being conditioned to do things the Windows way, are stages that many users go through, and they do have the potential to break things. Many users here have already passed through that phase.
The potentially-breaking changes that you're going to make, though, are to text files. It's trivial to make a copy of them before you fiddle. When things ultimately go pear-shaped, it's a matter of moments to move it back even if you only have a command line or, in really dire circumstances, a live USB to work from, and your machine is magically repaired.
Failing that, a reinstall-and-restore-from-backups takes about 20 minutes.
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